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research article
Stereoselective total synthesis of (-)-galantinic acid
2006
A concise, practical and stereoselective total synthesis of galantinic acid, constituent of the peptide antibiotic galantin, is reported. The title compound is obtained in six steps via Heathcock-Claisen condensation, Evans reduction and deprotection in 10% overall yield from protected serine. The route described herein thus constitutes the shortest and most efficient procedure for the preparation of the title compound disclosed so far.
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postprint_SL_2006_1580.pdf
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s-2006-941602.pdf
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