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research article
Preparation and NMR structure of the cyclo-β-tripeptide [β3-HGlu] in aqueous solution. A new class of enterobactin-type C3-symmetrical ligands?
By exploiting the solubilizing effect of LiCl on peptides in THF, the water-sol. title compd. could be prepd., and its structure was detd. by NMR. Structural similarities and differences between the trilactam ring of [beta3-HGlu]3 and the corresponding trilactone ring, such as that of enterobactin, are discussed, and structures are proposed that should be able to serve as tridentate or trivalent ligands for metal centers.
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Name
007 Helvet. Chim. Act. 1999, 82, 957.pdf
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