Direct piezoelectric effect in relaxor-ferroelectric single crystals

Direct measurements of longitudinal (d(33)) and transverse (d(31)) piezoelectric coefficients have been made on cuboid samples of [001](C)-poled 0.955Pb[Zn1/3Nb2/3]O-3-0.045PbTiO(3) (PZN-4.5PT) and 0.68Pb[Mg1/3Nb2/3]O-3-0.32PbTiO(3) (PMN-32PT) single crystals. The measurements were made in a Berlincourt-type press over a wide range of dynamic and static bias stresses. In the transverse mode, the response was found to be essentially anhysteretic and d(31) was independent of the dynamic stress amplitude. In contrast, for the longitudinal mode, the piezoelectric charge-stress behavior is hysteretic. Moreover, the relative hysteresis size and the d(33) coefficient are both strong functions of bias stress, dynamic stress amplitude, and frequency; coupling of the dynamic stress dependency of d(33) to the charge-stress hysteresis is demonstrated by a quasi-Rayleigh-type relationship. The observed hysteretic response could be due to domain switching in the crystals although this would be unexpected for a [001](C)-poled rhombohedral crystal. Instead, following the observed difference between transverse and longitudinal behaviors, it is suggested that polarization rotation away from the poling direction leads to a hysteretic response. (C) 2004 American Institute of Physics.


Published in:
Journal of Applied Physics, 95, 10, 5679-5684
Year:
2004
ISSN:
0021-8979
Keywords:
Note:
Davis, M EPFL, Swiss Fed Inst Technol, Dept Mat, Ceram Lab, CH-1015 Lausanne, Switzerland EPFL, Swiss Fed Inst Technol, Dept Mat, Ceram Lab, CH-1015 Lausanne, Switzerland
818UF
Times Cited:6
Cited References Count:28
Other identifiers:
Laboratories:




 Record created 2006-08-21, last modified 2018-03-17


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)