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research article

Piezoelectric properties of perovskite ferroelectrics: Unsolved problems and future research

Damjanovic, D.  
2001
Annales De Chimie-Science Des Materiaux

This article reviews recent advances in the studies of the piezoelectric properties of perovskite materials. Perovskite compositions are the best known and the largest family of ferroelectric and piezoelectric materials.: The dependence of the longitudinal, d(33), piezoelectric:coefficient on crystallographic orientation was examined in single crystals of BaTiO3, PbTiO3, Pb(Zr,Ti)O-3, KNbO3, relaxor-ferroelectric solid solutions [e.g. Pb(Mg1/3Nb2/3)O-3-PbTiO3 and Pb(Zn1/3Nb2/3)O-3-PbTiO3] and Na1/2Bi1/2TiO3. In most cases the largest piezoelectric coefficient was found in a direction which does not coincide with the polarization direction. In relaxer ferroelectrics, some compositions near the morphotropic phase boundary (MPB) exhibit very large piezoelectric (> 2000 pC/N) and coupling coefficients (k(33)> 90%) These results are-discussed in terms of so-called engineered domain structure and crystal anisotropy. The article also discusses evidence for the presence of a monoclinic phase between the rhombohedral and tetragonal phases at the MPB in Pb(Zr, Ti)O-3.

  • Details
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Type
research article
Web of Science ID

WOS:000169032300019

Author(s)
Damjanovic, D.  
Date Issued

2001

Published in
Annales De Chimie-Science Des Materiaux
Volume

26

Issue

1

Start page

99

End page

106

Subjects

morphotropic phase-boundary

•

lead-zirconate-titanate

•

crystal orientation dependence

•

single-crystals

•

solid-solution

•

thin-films

•

ceramics

•

behavior

•

strain

•

system

Note

Damjanovic, D Ecole Polytech Fed Lausanne, Dept Mat, Ceram Lab, DMX,LC, CH-1015 Lausanne, Switzerland Ecole Polytech Fed Lausanne, Dept Mat, Ceram Lab, DMX,LC, CH-1015 Lausanne, Switzerland

438AV

Cited References Count:27

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233442
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