Selective Deprotection Method Using Palladium Water Soluble Catalysts

• Published in: Tetrahedron Letters, vol. 35, num. 47, p. 8783-8786
• Publication date: 1994

Allylcarboxy and Allyloxycarbonyl groups can be removed without affecting dimethylallylcarboxy and cinnamylcarboxy groups in the same molecule. using Pd(0) water soluble catalyst prepared in situ, with diethylamine as allyl scavenger. Homogeneous or biphasic media are suitable: the yields of deprotection are quantitative.

Reference

• LGSA-ARTICLE-2006-011

Record created on 2006-06-16, modified on 2017-05-12