Micro-structured string-reactor for autothermal production of hydrogen

Novel micro-structured string-reactor designed as catalytically active wires placed in parallel into a tube was developed. The small diam. of the channels (.apprx.100 mm) leads to a short radial diffusion time, a narrow residence time distribution, and a low pressure drop. This reactor was applied for the oxidative steam-reforming of methanol to produce hydrogen in autothermal mode for fuel cells. The heat generated during methanol oxidn. at the reactor entrance is axially transferred to the reactor zone of the endothermic steam-reforming. The brass metal wires (Cu/Zn = 4/1) were used as precursors for the prepn. of string-catalysts. The brass wires have high thermal cond. (120 W/(m K)) and the chem. compn. is similar to the active phase of the Cu/ZnO/Al2O3 traditional catalyst during the steam-reforming of methanol. Brass-based string catalysts are obtained by metal/aluminum alloy formation on the outer surface of wires followed by an acid treatment leaching out aluminum. This treatment leads to an increase of the sp. surface area due to the formation of porous outer layer on the wire surface. The porous outer layer has the morphol. of Raney metals. The catalysts were first tested for the steam-reforming of methanol and showed high activity together with selectivities close to 100% towards hydrogen and carbon dioxide. Then, the optimized catalyst was tested during the methanol partial oxidn. and during steam reforming. Oxygen was obsd. to be totally converted via total oxidn. and therefore, higher methanol conversion in steam reforming together with CO2 selectivity of 99% and H2 selectivity of 60% were obtained. [on SciFinder (R)]


Published in:
Chemical Engineering Journal, 101, 1-3, 3-9
Year:
2004
Keywords:
Note:
CAN 141:159281 49-1 Industrial Inorganic Chemicals EPFL-LGRC,Swiss Federal Institute of Technology,Lausanne,Switz. Journal 1385-8947 written in English. 12621-87-3; 12683-02-2 Role: CAT (Catalyst use), CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process), USES (Uses) (aluminum-coated; microstructured string reactor contg. parallel brass wires for autothermal prodn. of hydrogen from methanol by oxidn.-reforming); 7429-90-5 (Aluminum) Role: CAT (Catalyst use), CPS (Chemical process), PEP (Physical, engineering or chemical process), REM (Removal or disposal), PROC (Process), USES (Uses) (coating, on brass wires; microstructured string reactor contg. parallel brass wires for autothermal prodn. of hydrogen from methanol by oxidn.-reforming); 7647-01-0 (Hydrochloric acid) Role: NUU (Other use, unclassified), USES (Uses) (leaching solvent, for aluminum-coated brass wires; microstructured string reactor contg. parallel brass wires for autothermal prodn. of hydrogen from methanol by oxidn.-reforming); 67-56-1 (Methanol) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (oxidn.-reforming of; microstructured string reactor contg. parallel brass wires for autothermal prodn. of hydrogen from methanol by oxidn.-reforming)
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 Record created 2006-04-18, last modified 2018-01-27

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