A new non-stationary process for the production of ethyl acetate

When adding C2H4 to AcOH over a H2SO4-SiO2 catalyst to give AcOEt, the activity of the solid-bed catalyst depended on the surface of the carrier; best results were obtained with SiO2 with a surface area of 120 m2/g. In a stationary process, the space-time-yield curve peaked at .apprx.130 h operating time, then decreased to approx. half this value over the next 300 h, whereas in a nonstationary process, the space-time-yield curve peaked at 100 h and did not decrease during the next 400 h of operation. [on SciFinder (R)]


Published in:
Chemie Ingenieur Technik, 49, 8, 667
Year:
1977
Keywords:
Note:
CAN 87:167509
23-17
Aliphatic Compounds
Hoechst A.-G.,Frankfurt/Main,Fed. Rep. Ger.
Journal
0009-286X
written in German.
74-85-1 Role: RCT (Reactant), RACT (Reactant or reagent) (addn. reaction of, with acetic acid, nonstationary process for); 64-19-7 Role: RCT (Reactant), RACT (Reactant or reagent) (addn. reaction of, with ethylene, nonstationary process for); 141-78-6P Role: PREP (Preparation) (manuf. of, from acetic acid and ethylene by nonstationary process)
Laboratories:




 Record created 2006-04-18, last modified 2018-01-27


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