1H, 19F-HOESY and PGSE diffusion studies on ionic liquids: The effect of co-solvent on structure
Nama, D; Kumar, PGA; Pregosin, PS; Geldbach, TJ; Dyson, PJ
2006
Download
Formats
Format
BibTeX
MARCXML
TextMARC
MARC
DublinCore
EndNote
NLM
RefWorks
RIS

Files

Abstract

1H, 19F-HOESY studies on the ionic liq. based on 1-butyl-3-methylimidazolium tetrafluoroborate, [C4C1i.m.]BF4, [C4C1i.m.][N(OTf)2], and, partially, [C4C1i.m.]PF6, are reported. The addn. of methanol separates the ions; however, in dichloromethane soln. the anions and cations show strong HOESY contacts even after diln. and taken together with the PGSE diffusion measurements, the data suggest strong ion pairing in this solvent.

Details

Title 1H, 19F-HOESY and PGSE diffusion studies on ionic liquids: The effect of co-solvent on structure
Author(s) Nama, D ; Kumar, PGA ; Pregosin, PS ; Geldbach, TJ ; Dyson, PJ
Published in INORGANICA CHIMICA ACTA
Volume 359
Issue 6
Pages 1907-1911
Date 2006
DOI https://doi.org/10.1016/j.ica.2005.09.015
Other identifier(s) View record in Web of Science
DAR: 8446
Laboratories LCOM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-03-30

PDF