O-Fluoromethyl carboxylates and O-fluoromethyl carbamates
The fluoride catalyzed reaction between acyl fluorides and monomeric formaldehyde affords fluoromethyl carboxylates in acceptable yields. Fluoromethyl fluoroformate, readily accessible from the corresponding dichloro compd., condenses with amines to give fluoromethyl carbamates. [on SciFinder (R)]
1995
51
20
5807
12
CAN 123:142990
21-2
General Organic Chemistry
Inst. CHim. Org.,Univ. Batiment Chim.,Lausanne-Dorigny,Switz.
Journal
written in English.
5342-31-4P (Methylene dibenzoate); 20177-68-8P; 32720-34-6DP; 166331-88-0P; 166331-89-1P Role: BYP (Byproduct), PREP (Preparation) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 17455-13-9 (18-Crown-6); 59201-86-4 (Tris(diethylamino)sulfonium difluorotrimethylsilicate) Role: CAT (Catalyst use), USES (Uses) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 7789-23-3 (Potassium fluoride) Role: CAT (Catalyst use), RCT (Reactant), USES (Uses), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 100-46-9 (Benzylamine); 104-94-9 (p-Anisidine); 109-73-9 (Butylamine); 136-95-8 (2-Aminobenzothiazole); 288-32-4 (Imidazole); 334-19-0 (Heptanoyl fluoride); 455-32-3 (Benzoyl fluoride); 693-34-5 (Adipoyl fluoride); 1977-87-3 (Cyclohexanecarbonyl fluoride); 22128-62-7 (Chloromethyl chloroformate); 31174-04-6 (2-Furoyl fluoride) Role: RCT (Reactant), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 2838-04-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 166331-78-8P; 166331-79-9P; 166331-80-2P; 166331-81-3P; 166331-82-4P; 166331-83-5P; 166331-84-6P; 166331-85-7P; 166331-86-8P; 166331-87-9P Role: SPN (Synthetic preparation), PREP (Preparation) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 50-00-0 (Formaldehyde) Role: RCT (Reactant), RACT (Reactant or reagent) (monomeric; O-fluoromethyl carboxylates and O-fluoromethyl carbamates)
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