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research article

The Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles

Schlosser, Manfred  
•
Keller, Holger
1995
Liebigs Annalen

Starting with 1,1,1-trifluoroacetone, 3-(trifluoromethyl)-1-(trimethylsilyloxy)-1,3-butadiene has been prepd. as a mixt. of (Z) and (E) isomers. The diene undergoes [4 + 2] cycloaddn. reactions with a variety of dienophiles affording trifluoromethyl-substituted carbocyclic and heterocyclic compds. in yields ranging from moderate to good. [on SciFinder (R)]

  • Details
  • Metrics
Type
research article
DOI
10.1002/jlac.1995199509221
Author(s)
Schlosser, Manfred  
Keller, Holger
Date Issued

1995

Published in
Liebigs Annalen
Issue

9

Start page

1587

End page

9

Subjects

Diels-Alder reaction (Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles); Dienophiles Role: RCT (Reactant)

•

SPN (Synthetic preparation)

•

PREP (Preparation)

•

RACT (Reactant or reagent) (Diels-Alder route to trifluoromethyl-substitu

•

carbocycle prepn trifluoromethylated Diels Alder route; heterocycle prepn trifluoromethylated Diels Alder route

Note

CAN 124:55071 21-2 General Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0947-3440 written in English. 421-50-1 (1,1,1-Trifluoroacetone); 545-06-2 (Trichloroacetonitrile); 623-47-2 (Ethyl propiolate); 670-54-2 (TCNE); 762-42-5 (Dimethyl acetylenedicarboxylate); 7020-80-6; 7206-05-5; 23521-49-5 Role: RCT (Reactant), RACT (Reactant or reagent) (Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles); 103313-68-4P; 128722-19-0P; 172264-38-9P; 172264-39-0P; 172264-40-3P; 172264-41-4P; 172264-42-5P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles); 583-02-8P; 728-47-2P; 172264-43-6P; 172264-44-7P; 172264-45-8P Role: SPN (Synthetic preparation), PREP (Preparation) (Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCO  
Available on Infoscience
March 3, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/226916
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