A shortcut to a-santalol
a-Santalol (Z-I) can be prepd. from the readily available 8-bromotricyclene (II) in a one-flask procedure under perfect regio- and stereocontrol. [on SciFinder (R)]
1993
34
34
5441
4
CAN 120:107378
30-15
Terpenes and Terpenoids
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
152578-86-4 Role: RCT (Reactant), RACT (Reactant or reagent) (agent for hydroxylation of a-santalene); 52645-83-7 Role: RCT (Reactant), RACT (Reactant or reagent) (alkylation by, of potassioisoprene, a-santalene from); 152096-85-0 Role: RCT (Reactant), RACT (Reactant or reagent) (coupling reaction of, with (methallyl)magnesium chloride); 152096-83-8P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and epoxide rearrangement of); 22527-23-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and hydroxylation of, regio- and stereocontrol in); 152186-23-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and isomerization of); 153838-36-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and oxidn. of); 19903-70-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and redn. of); 115-71-9P (a-Santalol); 14490-17-6P; 152096-84-9P; 152186-24-8P; 152186-25-9P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 152186-26-0 Role: RCT (Reactant), RACT (Reactant or reagent) (tosylation of)
REVIEWED