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Journal article

A one-pot synthesis of coumaryl, coniferyl, and sinapyl alcohol

The side chain of 4-allylphenols was easily deprotonated by BuLi-KOCMe3. Consecutive treatment with FB(OMe)2 and H2O2 afforded the title alcs. I (R = H, R1 = H, OMe; R = R1 = OMe). [on SciFinder (R)]

    Keywords: Hydroxylation (isomerization and ; of allylphenols) ; allylphenol hydroxylation isomerization; coumaryl alc; coniferyl alc; sinapyl alc

    Note:

    CAN 115:28970

    26-9

    Biomolecules and Their Synthetic Analogs

    Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.

    Journal

    0040-4039

    written in English.

    97-53-0 (Eugenol); 501-92-8 (4-Allylphenol); 6627-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (hydroxylation and isomerization of); 118-34-3P (Syringin); 458-35-5P (Coniferyl alcohol); 531-29-3P (Coniferin); 537-33-7P (Sinapyl alcohol); 20649-40-5P (Coumaryl alcohol); 134660-05-2P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 572-09-8 (Acetobromoglucose) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with hydroxypropenylphenols)

    Reference

    Record created on 2006-03-03, modified on 2016-08-08

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