Journal article

Monomeric formaldehyde in ethereal solution

Ethereal solns. of monomeric formaldehyde can be conveniently prepd. from paraformaldehyde and p-toluenesulfonic anhydride and offer practical advantages in org. synthesis. [on SciFinder (R)]

    Keywords: Hydroxymethylation (by monomeric formaldehyde in ethereal solns.) ; formaldehyde monomer prepn THF soln; hydroxymethylation formaldehyde THF soln


    CAN 114:163478


    Aliphatic Compounds

    Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.



    written in English.

    75-25-2 (Tribromomethane); 156-60-5; 372-18-9 (1,3-Difluorobenzene) Role: RCT (Reactant), RACT (Reactant or reagent) (lithiation and subsequent hydroxymethylation of, with monomeric formaldehyde in ether); 75-80-9P; 19064-18-7P; 36712-42-2P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 50-00-0P (Formaldehyde) Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of, from paraformaldehyde in ethers, as hydroxymethylation reagent); 4124-41-8 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with paraformaldehyde in ethers, monomer from); 30525-89-4 (Paraformaldehyde) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with toluenesulfonic anhydride in ethers, monomer from)


    • LSCO-ARTICLE-1990-003

    Record created on 2006-03-03, modified on 2016-08-08


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