Infoscience

Journal article

Ene-sulfides as reaction partners of organometallic compounds

Whereas Ph substituted-vinyl ethers undergo lithiation at either an allylic C or the C attached to the O, the sulfides are lithiated predominantly at the C attached to the S. [on SciFinder (R)]

    Keywords: Metalation (of vinyl sulfides) ; lithiation vinyl sulfide ether

    Note:

    CAN 84:89748

    25-10

    Noncondensed Aromatic Compounds

    Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.

    Journal

    0018-019X

    written in English.

    58431-65-5P; 58431-66-6P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and lithiation of); 4922-47-8P; 23261-38-3P; 35347-59-2P; 53847-74-8P; 58431-67-7P; 58431-68-8P; 58431-69-9P; 58431-70-2P; 58431-71-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 78-84-2 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with [(phenylthio)methyl]triphenylphosphonium chloride-butyllithium reaction product); 1822-73-7; 15436-04-1; 16336-50-8; 21106-25-2; 21106-26-3 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with butyllithium); 882-33-7 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with cyclohexenyllithium); 37609-34-0 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with diphenyl disulfide); 598-30-1 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with phenyl vinyl ether); 766-94-9 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with sec-butyllithium); 630-19-3 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with ylide from [(phenylthio)methyl]triphenylphosphonium chloride); 13884-92-9; 58431-64-4 Role: RCT (Reactant), RACT (Reactant or reagent) (vinyl sulfide formation from); 75-07-0 Role: RCT (Reactant), RACT (Reactant or reagent) (with [(phenylthio)ethyl]triphenylphosphonium iodide-butyllithium reaction products); 109-72-8 Role: RCT (Reactant), RACT (Reactant or reagent) (with vinyl sulfides)

    Reference

    Record created on 2006-03-03, modified on 2016-08-08

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