Die Einwirkung von Metall-Alkoholaten auf cis- und trans-Styrylchlorid

The alcoholate-induced dehydrochlorination of styryl chloride possibly occurs by the 3 different competing mechanisms: E2, E1cb, and E1cb-HBA an E1cb modification. These conclusions were confirmed by H-D exchange, isotope effects, order of reaction, and relative elimination rates as a function of the cis or trans configuration of the material and of the nature of the base (EtONa or tert-BuOK.) [on SciFinder (R)]


Published in:
Chemische Berichte, 104, 9, 2873-2884
Year:
1971
Keywords:
Note:
CAN 75:140083 22 Physical Organic Chemistry Org.-Chem. Inst.,Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0009-2940 written in German. 4110-77-4; 4604-28-8 Role: RCT (Reactant), RACT (Reactant or reagent) (dehydrochlorination of, mechanism of); 7782-39-0 Role: PRP (Properties) (isotopic effect of, on dehydrochlorination of styryl chloride)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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