Eine Methode zur Epimerisierung von 1,2-Diolen

Diols, meso- and dl-PrCH(OH)CH(OH)Pr, cis- and trans-1,2-cyclohexanediol, 9,10,-cis-dihydroxy-cis,trans-1,5-cyclododecadiene, trans-7,8-dihydroxybicyclo[4.2.0]octane, and I, are epimerized by heating their dilithium diolates in (MeOCH2CH2)2O in 55-78% yields. [on SciFinder (R)]


Published in:
Synthesis, 5, 257
Year:
1970
Keywords:
Note:
CAN 73:55205 21 General Organic Chemistry Org.-Chem. Inst.,Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0039-7881 written in German. 1460-57-7; 1792-81-0; 15584-48-2; 16991-05-2; 22520-40-7; 22520-41-8; 29118-70-5 Role: RCT (Reactant), RACT (Reactant or reagent) (epimerization of)
Laboratories:




 Record created 2006-03-03, last modified 2018-04-18


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