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research article
Monofluorocarbene and its syn-anti selectivity
syn-Substituted cyclopropanes (syn-I) (R, R1, and X are above the plane) and anti-I (X is below the plane) are prepd. from R1R3C:CRR2 and :CHF (from Br2CHF and BuLi). syn- and anti-I(X = Cl) are also prepd.; the syn-anti ratios for I(X = F and X = Cl) are similar. The formation of syn-transition states is discussed. [on SciFinder (R)]
Type
research article
Authors
Publication date
1968
Published in
Volume
7
Issue
10
Start page
820
End page
821
Note
CAN 70:11161 24 Alicyclic Compounds Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0570-0833 written in English. 13453-52-6 Role: PROC (Process) (addn. of, to olefins)
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
March 3, 2006
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