000080609 001__ 80609
000080609 005__ 20181203020248.0
000080609 0247_ $$2doi$$a10.2533/chimia.2008.287
000080609 02470 $$2ISI$$a000255973000024
000080609 02470 $$2DAR$$a12414
000080609 037__ $$aARTICLE
000080609 245__ $$aEXAFS structural determination of the Pt2(P2O5H2)44- anion in solution
000080609 269__ $$a2008
000080609 260__ $$c2008
000080609 336__ $$aJournal Articles
000080609 500__ $$aCAN 149:564309
000080609 500__ $$a65-5
000080609 500__ $$aGeneral Physical Chemistry
000080609 500__ $$aLaboratoire Spectroscopic Ultrarapide,Ecole Polytechnique Federale de Lausanne,Lausanne,Switz.
000080609 500__ $$aJournal
000080609 500__ $$a0009-4293
000080609 500__ $$awritten in English.
000080609 500__ $$a102532-42-3 Role: PRP (Properties) (EXAFS structural detn. of Pt2(P2O5H2)44- anion in soln.)
000080609 520__ $$aWe present the first structural detn. of the Pt2(P2O5H2)44- anion in soln. by analyzing the extended X-ray absorption fine structure (EXAFS) spectrum of the Pt LIII edge. The data could be fit with a simple model involving single and multiple scattering paths to near and far P-atoms, bridging O-atoms, and the other Pt-atom in the binuclear complex. A Pt-Pt distance of 2.876(28) .ANG. and a Pt-P bond length of 2.32(4) .ANG. are obtained. These values are in line with distances found in previous X-ray diffraction studies. The assignment of the EXAFS spectrum of the Pt2(P2O5H2)44- anion in its ground state is required for future time-resolved X-ray absorption measurements with the goal of detg. the structure and dynamics of the complex in the 1,3A2u excited states.
000080609 6531_ $$aEXAFS spectra; Molecular structure; Solution structure (EXAFS structural detn. of Pt2(P2O5H2)44- anion in soln.)
000080609 6531_ $$aEXAFS structural detn platinum pyrophosphite anion soln
000080609 700__ $$0242234$$g176332$$avan der Veen, Renske M.
000080609 700__ $$0242228$$g174257$$aMilne, Christopher J.
000080609 700__ $$0240466$$g168768$$aPham, Van-Thai
000080609 700__ $$0240046$$g167896$$aEl Nahhas, Amal
000080609 700__ $$aWeinstein, Julia A.
000080609 700__ $$aBest, Jonathan
000080609 700__ $$aBorca, Camelia N.
000080609 700__ $$aBressler, Christian$$g157913$$0240467
000080609 700__ $$aChergui, Majed$$g122830$$0240045
000080609 773__ $$j62$$tChimia$$k4$$q287-290
000080609 909C0 $$xU10862$$0252026$$pLSU
000080609 909CO $$pSB$$particle$$ooai:infoscience.tind.io:80609
000080609 937__ $$aLSU-ARTICLE-2008-012
000080609 970__ $$a273/LSU
000080609 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000080609 980__ $$aARTICLE