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research article
The Occurrence of Non-Gaussian Spectral Line Shapes of Molecules in Electrostatically Disordered Media
We calc. the effects of relatively strong elec. fields, corresponding to typical values for the fields inside glasses and proteins, on the spectroscopic properties of a simple two-level mol. Disorder in the elec. field strength is employed as a phys. source for inhomogeneous broadening. A striking result is that a Gaussian probability distribution for the field over the ensemble does not give rise to a Gaussian spectral line shape. The results are used to describe the absorption spectra of the B800 band of the B800-850 light-harvesting complex of photosynthetic purple bacteria. [on SciFinder (R)]
Type
research article
Authors
Publication date
2001
Published in
Volume
105
Issue
40
Start page
9715
End page
9718
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 27, 2006
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