Density matrix propagation and stationary absorption spectra: HCl in rare gas matrixes

The computation of stationary optical spectra of mol. systems based on a wavepacket propagation on excited potential energy surfaces (PES) is extended to the condensed phase case in utilizing the d. matrix theory. As an example, a one-dimensional model is studied for the photodissocn. of matrix isolated HCl. Emphasis is put on the interplay of the cage effect and the energy dissipation into the matrix. [on SciFinder (R)]


Published in:
Femtochemistry: Ultrafast Chemical and Physical Processes in Molecular Systems, 309-312
Year:
1996
Laboratories:




 Record created 2006-02-27, last modified 2018-03-17


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