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  4. Self-refocusing effect of 270 Deg Gaussian pulses: applications to selective two-dimensional exchange spectroscopy
 
research article

Self-refocusing effect of 270 Deg Gaussian pulses: applications to selective two-dimensional exchange spectroscopy

Emsley, Lyndon  
•
Bodenhausen, Geoffrey  
1989
Journal of Magnetic Resonance [1969-1992]

A soln. is presented to the problem of phase dispersion in the resultant magnetization for pulses used for high-resoln. NMR work by demonstrating how a Gaussian pulse having an on-resonance flip angle of 270 Deg has much improved phase properties over the conventional 90 Deg Gaussian pulse. Since the whole pulse is soft, the coupling partners of a multiplet are not affected, and the evolution of the magnetization due to couplings will be refocused in exactly the same way as if it were due to chem. shifts. An illustrative spectrum of a mixt. of cis- and trans-2-phenylcyclopropanecarboxylic acid Me ester obtained with a hard 90 Deg pulse is presented. [on SciFinder (R)]

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Type
research article
DOI
10.1016/0022-2364(89)90185-6
Author(s)
Emsley, Lyndon  
Bodenhausen, Geoffrey  
Date Issued

1989

Publisher

Academic Press

Published in
Journal of Magnetic Resonance [1969-1992]
Volume

82

Issue

1

Start page

211

End page

21

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRMB  
LRM  
Available on Infoscience
February 22, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225530
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