Longitudinal relaxation pathways in scalar-coupled systems

In applications to systems with resolved scalar couplings, the 2-dimensional exchange expt. (NOESY: nuclear Overhauser effect spectroscopy) can provide greatly increased information if the flip angles of the 2 pulses that precede and follow the mixing interval tm are reduced (typically b ~ 20 Deg). The anal. of the amplitudes of individual signals within diagonal- and cross-peak multiplets allows one to gain insight into a variety of competing longitudinal relaxation mechanisms, not only for the fast- and slow-motion limits but also, in favorable cases, for crit. correlation times. [on SciFinder (R)]

Published in:
Journal of Magnetic Resonance, 81, 1, 13-42

 Record created 2006-02-22, last modified 2018-03-18

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