P5X2+ (X = Br, I), a phosphorus-rich binary P-X cation with a C2v-symmetric P5 cage
Krossing, Ingo; Raabe, Ines
2001

Abstract

Insertion of the intermediately formed carbene-analogous PX24 ion (X = Br, I) into one of the P-P bonds of the P4 tetrahedron led to the P5X2+ ion - the 1st example of the previously unknown class of phosphorus-rich binary P-X cations. The crystal structure of [P5Br2]+[Al{OC(CF3)3}]- was detd. and mol. structure calcns. were performed on both the bromide and iodide analogs. [on SciFinder (R)]

Details

Title P5X2+ (X = Br, I), a phosphorus-rich binary P-X cation with a C2v-symmetric P5 cage
Author(s) Krossing, Ingo ; Raabe, Ines
Published in Angewandte Chemie, International Edition
Volume 40
Issue 23
Pages 4406-4409
Date 2001
DOI https://doi.org/10.1002/1521-3773(20011203)40:23<4406::AID-ANIE4406>3.0.CO;2-X
Laboratories LCIC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LCIC - Laboratory of Inorganic and Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-02-15

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