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research article
Ag(P4)2+: the first homoleptic metal-phosphorus cation
[Ag(P4)2][Al((F3C)CO2)4], with the tetrahedral P4 mol. as ligand, was prepd. and its crystal structure and Raman spectra detd. The Ag coordination is nearly planar and the calcd. mol. orbitals of the cation indicate the electronic basis for this geometry. [on SciFinder (R)]
Type
research article
Authors
Publication date
2001
Published in
Volume
123
Issue
19
Start page
4603
End page
4604
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 15, 2006
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