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research article
Combinatorial synthesis of bimetallic complexes with three halogeno bridges
Methods for the synthesis of bimetallic complexes in which two different metal fragments are connected by three chloro or bromo bridges are reported. The reactions are general, fast, and give rise to structurally defined products in quantitative yields. Therefore, they are ideally suited for generating a library of homo- and heterobimetallic complexes in a combinatorial fashion. This is of special interest for applications in homogeneous catalysis. Selected members of this library were synthesized and comprehensively characterized; single-crystal X-ray analyses were performed for 15 new bimetallic compounds.
Type
research article
Web of Science ID
WOS:000221969300020
Authors
Publication date
2004
Published in
Volume
10
Issue
11
Start page
2811
End page
2821
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 9, 2006
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