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research article
Photoelectron Spectroscopy of Doped Helium Droplets
The photoionization dynamics of aniline doped helium droplets has been investigated by photoelectron spectroscopy. The photoelectron spectra resemble closely that of gas phase aniline, except for a dropletsize- dependent shift. This shift is caused by lowering of the ionization threshold upon solvation and can be readily estimated. The individual peaks in the photoelectron spectrum are broadened towards lower kinetic energy which is attributed to the relaxation of the photoelectrons as they pass through the helium droplet.
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Type
research article
Web of Science ID
WOS:000232558400025
Authors
Publication date
2005
Published in
Volume
95
Issue
16
Article Number
163401
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
December 16, 2005