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  4. Influence of the functional group on the synthesis of aminophosphines, diphosphinoamines and iminobiphosphines
 
research article

Influence of the functional group on the synthesis of aminophosphines, diphosphinoamines and iminobiphosphines

Fei, ZF  
•
Scopelliti, R  
•
Dyson, PJ  
2003
Dalton Transactions

The reaction of the anilines RNH2 [R = C6H4(o-CN), C6H4(p-CN), C6H4(m-CN), C6H4(o-C6H5), C6F5 and C6H4(o-CF3)] with Ph2PCl and inorganic or organic bases in differing stoichiometry and in different solvents has been studied. The electronic properties and steric effects of the substituent groups, the base employed, the stoichiometry and the solvent all influence the outcome of the reaction and a series of aminophosphines, diphosphinoamines and iminobiphosphines have been isolated and characterised. The structures of three diphosphinoamines and three iminobiphosphines have been established using single-crystal X-ray diffraction.

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Type
research article
DOI
10.1039/B303645F
Author(s)
Fei, ZF  
Scopelliti, R  
Dyson, PJ  
Date Issued

2003

Published in
Dalton Transactions
Issue

13

Start page

2772

End page

2779

Subjects

phosphorus-nitrogen chemistry

•

ligands (ph2p)(2)nh dppa

•

mixed-metalclusters

•

coordination chemistry

•

lithium-salts

•

complexes

•

amine

•

palladium(ii)

•

platinum(ii)

•

phosphine

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
Available on Infoscience
November 9, 2005
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/219882
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