000059806 001__ 59806
000059806 005__ 20180317093452.0
000059806 022__ $$a1477-9226
000059806 02470 $$2DAR$$a3246
000059806 02470 $$2ISI$$a000181342800031
000059806 037__ $$aARTICLE
000059806 245__ $$aCrystal structure and fluxional behaviour in solution of [Rh-4(CO)(6)(mu-Me2PCH2PMe2)(3)]
000059806 260__ $$c2003
000059806 269__ $$a2003
000059806 336__ $$aJournal Articles
000059806 520__ $$a[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridging one edge of the same Rh-3 face. The result is an imbalance of the formal electron count at two rhodium atoms. As observed by C-13- and P-31-NMR, the mobility of the ligands is restricted to one mu-CO <-> eta-CO site exchange which astonishingly does not average dynamically the electron count on all four metal atoms.
000059806 6531_ $$acluster complexes
000059806 6531_ $$adynamics
000059806 6531_ $$aligand
000059806 6531_ $$arh-4(co)(12)
000059806 6531_ $$aderivatives
000059806 700__ $$aBesancon, K
000059806 700__ $$aLumini, T
000059806 700__ $$0240013$$aLaurenczy, G$$g123171
000059806 700__ $$0241751$$aDetti, S$$g148281
000059806 700__ $$aSchenk, K
000059806 700__ $$0241837$$aRoulet, R$$g123536
000059806 773__ $$k5$$q968-972$$tDALTON TRANSACTIONS
000059806 909CO $$ooai:infoscience.tind.io:59806$$particle$$pSB
000059806 909C0 $$0252010$$pLCOM$$xU9
000059806 937__ $$aLCOM-ARTICLE-2003-006
000059806 970__ $$aISI:000181342800031/LCOM
000059806 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000059806 980__ $$aARTICLE