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  4. Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]
 
research article

Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Laurenczy, G  
•
Faure, M
•
Vieille-Petit, L
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2002
ADVANCED SYNTHESIS & CATALYSIS

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation (eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.

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Type
research article
DOI
10.1002/1615-4169(200212)344:10<1073::AID-ADSC1073>3.0.CO;2-J
Web of Science ID

WOS:000180078900006

Author(s)
Laurenczy, G  
Faure, M
Vieille-Petit, L
Suss-Fink, G
Ward, TR
Date Issued

2002

Published in
ADVANCED SYNTHESIS & CATALYSIS
Volume

344

Issue

10

Start page

1073

End page

1077

Subjects

aqueous-solution

•

complexes

•

exchange

•

activation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
Available on Infoscience
November 9, 2005
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/219866
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