Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Laurenczy, G; Faure, M; Vieille-Petit, L; Suss-Fink, G; Ward, TR

doi:10.1002/1615-4169(200212)344:10&lt;1073::AID-ADSC1073&gt;3.0.CO;2-J

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Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Laurenczy, G ; Faure, M ; Vieille-Petit, L ; Suss-Fink, G[...]

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.

Published in:

ADVANCED SYNTHESIS & CATALYSIS, 344, 10, 1073-1077

Year:

2002

ISSN:

1615-4150

Keywords:

aqueous-solution ; complexes ; exchange ; activation

DOI:

10.1002/1615-4169(200212)344:10<1073::AID-ADSC1073>3.0.CO;2-J

Other identifiers:

DAR: 3750
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