Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]
Laurenczy, G; Faure, M; Vieille-Petit, L; Suss-Fink, G; Ward, TR
2002

Abstract

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.

Details

Title Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]
Author(s) Laurenczy, G ; Faure, M ; Vieille-Petit, L ; Suss-Fink, G ; Ward, TR
Published in ADVANCED SYNTHESIS & CATALYSIS
Volume 344
Issue 10
Pages 1073-1077
Date 2002
ISSN 1615-4150
Keywords
DOI 10.1002/1615-4169(200212)344:10<1073::AID-ADSC1073>3.0.CO;2-J
Other identifier(s) DAR: 3750
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Laboratories LCOM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
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Journal Articles
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