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research article
Reaction of Ru-3(CO)(12) with supermesityldiphosphene: a new type of reaction of a Group 8 transition metal carbonyl with a diphosphene
The reaction of (E)-bis(2,4,6-tri-tert-butylphenyl)diphosphene with Ru-3(CO)(12) results in cleavage of the P=P bond with concomitant C-H activation of one of the t-butyl groups to form Ru-3(mu-H)(2)(CO)(8)(mu-P-C6H2-2,4-Bu-t(2)-6-CMe2CH2)(2). The H-atoms have transferred from the ligand to the metal core. (C) 2002 Elsevier Science B.V. All rights reserved.
Use this identifier to reference this record
Type
research article
Web of Science ID
WOS:000178648800017
Authors
Publication date
2002
Published in
Volume
5
Issue
10
Start page
808
End page
810
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
November 9, 2005