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research article
One-pot, three-component synthesis of open-chain, polyfunctional sulfones
2002
Silyl enol ethers of esters, ketones, as well as allylstannane and allylsilanes react with sulfur dioxide activated with t-BuMe2SiOSO2CF3 to give silyl sulfinates that can be reacted in the same pot with a variety of electrophiles generating the corresponding polyfunctional sulfones. The silyl sulfinate intermediates are formed via ene-reactions following probably concerted mechanisms.
Type
research article
Web of Science ID
WOS:000173858900014
Authors
Publication date
2002
Published in
Issue
2
Start page
225
End page
231
Note
Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, Lausanne, Switzerland.
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
November 9, 2005
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