Regioselective Synthesis of 5-Endo,6-Endo-Dihydroxy-7-Oxabicyclo[2.2.1]Heptan-2-One with Differential Protection of the Diol Group

The introduction of two hydroxy groups with differential protection at the endo positions of C(5) and C(6) of the ''naked sugars of the first generation'' has been achieved by seleno-Pummerer rearrangement of 5-endo-hydroxy-6-exa-phenylseleno-7-oxabicyclo[2.2.1]heptan-2-one derivatives followed by deselenation with Bu(3)SnH.


Published in:
Synlett, 5, 420-422
Year:
1995
ISSN:
0936-5214
Keywords:
Note:
Univ lausanne,bch dorigny,chim sect,ch-1015 lausanne,switzerland.
Laboratories:




 Record created 2005-11-09, last modified 2018-03-17


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)