Homochiral Matching in the Diels-Alder Clyclodimerization 2-Vinyl-7-Oxabicyclo[2.2.1]Hept-2-Ene Derivatives

Racemic 6-vinyl-7-oxabicyclo[2.2.1]hept-5-en-2-one, 5-vinyl-7-oxabicyclo[2.2.1]hept-5-en-2-one and their ethylene acetals undergo highly stereoselective Diels-Alder cyclodimerizations. The optically pure semicyclic dienes give the corresponding optically pure dimers with the same ease.


Published in:
Tetrahedron Letters, 35, 1, 111-114
Year:
1994
ISSN:
0040-4039
Keywords:
Note:
Univ lausanne,chim sect,ch-1005 lausanne,switzerland.
Laboratories:




 Record created 2005-11-09, last modified 2018-03-17


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