The Diels-Alder adduct (+)-l of furan to 1-cyanovinyl (1'S)-camphanate was converted to methyl 3,5-O-diacetyl-2,6-dideoxy-beta-L-lyxo-hexofurano-side ((+)-12), a protected form of 2-deoxy-L-fucose, in 8 steps and 16.6% overall yield.
Titre
A Total, Asymmetric-Synthesis of 2-Deoxy-L-Fucose from Furan
Publié dans
Synthetic Communications
Volume
22
Numéro
13
Pages
1883-1893
Date
1992
ISSN
0039-7911
Note
Univ lausanne,chim sect,2 rue barre,ch-1005 lausanne,switzerland.
Date de création de la notice
2005-11-09