Synthesis and optical properties of water-soluble NIR absorbing star polypeptides based on functional rylene dyes

In this contribution, the synthesis of two novel amino-functionalized terrylene and quaterrylene diimide derivatives is described. These chromophores have been used as initiators for the ring-opening polymerization of N€-benzyloxycarbonyl-L-lysine N-carboxyanhydride. 4-Arm star polypeptides were obtained with number average chain lengths of 50 and 100 units. Removal of the N€-benzyloxycarbonyl side-chain protective groups afforded unprecedented water-soluble terrylene and quaterrylene based star polypeptides that combined high extinction coefficients in the NIR range with very good chemical and photostability.


Published in:
Polymer Bulletin, 52, 1, 57-64
Year:
2004
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 Record created 2005-07-07, last modified 2018-01-27


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