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  4. Organic Dye Photocatalyzed Synthesis of Functionalized Lactones and Lactams via a Cyclization-Alkynylation Cascade
 
research article

Organic Dye Photocatalyzed Synthesis of Functionalized Lactones and Lactams via a Cyclization-Alkynylation Cascade

Cavalli, Diana
•
Waser, Jerome  
May 13, 2024
Organic Letters

An organic dye photocatalyzed lactonization-alkynylation of easily accessible homoallylic cesium oxalates using ethynylbenziodoxolone (EBX) reagents has been developed. The reaction gave access to valuable functionalized lactones and lactams in up to 88% yield via the formation of two new C-C bonds. The transformation was carried out on primary, secondary, and tertiary homoallylic alcohols and primary homoallylic amines and could be applied to the synthesis of spirocyclic compounds as well as fused and bridged bicyclic lactones.

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OL2024-4235_Goldaccess.pdf

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Publisher

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http://purl.org/coar/version/c_970fb48d4fbd8a85

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openaccess

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CC BY

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9.17 MB

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Adobe PDF

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b35e7c95e00698d4de3380ea31e2d3c4

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