Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Scanning Tunneling Microscopy for Molecules: Effects of Electron Propagation into Vacuum
 
research article

Scanning Tunneling Microscopy for Molecules: Effects of Electron Propagation into Vacuum

Grewal, Abhishek
•
Leon, Christopher C.
•
Kuhnke, Klaus
Show more
April 29, 2024
Acs Nano

Using scanning tunneling microscopy (STM), we experimentally and theoretically investigate isolated platinum phthalocyanine (PtPc) molecules adsorbed on an atomically thin NaCl(100) film vapor deposited on Au(111). We obtain good agreement between theory and constant-height STM topography. We theoretically examine why strong distortions of STM images occur as a function of distance between the molecule and the STM tip. The images of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) exhibit for increasing distance, significant radial expansion due to electron propagation in the vacuum. Additionally, the imaged angular dependence is substantially distorted. The LUMO image has substantial intensity along the molecular diagonals where PtPc has no atoms. In the electronic transport gap, the image differs drastically from HOMO and LUMO even at energies very close to these orbitals. As the tunneling becomes increasingly off-resonant, the eight angular lobes of the HOMO or of the degenerate LUMOs diminish and reveal four lobes with maxima along the molecular axes, where both, HOMO and LUMO have little or no weight. These images are strongly influenced by low-lying PtPc orbitals that have simple angular structures.

  • Details
  • Metrics
Type
research article
DOI
10.1021/acsnano.3c12315
Web of Science ID

WOS:001224450000001

Author(s)
Grewal, Abhishek
Leon, Christopher C.
Kuhnke, Klaus
Kern, Klaus  
Gunnarsson, Olle
Date Issued

2024-04-29

Publisher

Amer Chemical Soc

Published in
Acs Nano
Volume

18

Issue

19

Start page

12158

End page

12167

Subjects

Physical Sciences

•

Technology

•

Scanning Tunneling Microscopy

•

Electronic Transportgap

•

Single Molecule Imaging

•

Decoupling Layer

•

Thin Insulator

•

Phthalocyanine

•

Nacl

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSEN  
FunderGrant Number

Max Planck Society

Available on Infoscience
June 5, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/208377
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés