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research article

Direct measurement of key exciton properties: Energy, dynamics, and spatial distribution of the wave function

Dong, Shuo
•
Puppin, Michele  
•
Pincelli, Tommaso
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June 1, 2021
Natural Sciences

Excitons, Coulomb-bound electron-hole pairs, are the fundamental excitations governing the optoelectronic properties of semiconductors. Although optical signatures of excitons have been studied extensively, experimental access to the excitonic wave function itself has been elusive. Using multidimensional photoemission spectroscopy, we present a momentum-, energy-, and time-resolved perspective on excitons in the layered semiconductor WSe2. By tuning the excitation wavelength, we determine the energy-momentum signature of bright exciton formation and its difference from conventional single-particle excited states. The multidimensional data allow to retrieve fundamental exciton properties like the binding energy and the exciton-lattice coupling and to reconstruct the real-space excitonic distribution function via Fourier transform. All quantities are in excellent agreement with microscopic calculations. Our approach provides a full characterization of the exciton properties and is applicable to bright and dark excitons in semiconducting materials, heterostructures, and devices.|Key points:|center dot The full life cycle of excitons is recorded with time- and angle-resolved photoemission spectroscopy.|center dot The real-space distribution of the excitonic wave function is visualized.|center dot Direct measurement of the exciton-phonon interaction.

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Type
research article
DOI
10.1002/ntls.10010
Web of Science ID

WOS:001190274100002

Author(s)
Dong, Shuo
Puppin, Michele  
Pincelli, Tommaso
Beaulieu, Samuel
Christiansen, Dominik
Huebener, Hannes
Nicholson, Christopher W.
Xian, Rui Patrick
Dendzik, Maciej
Deng, Yunpei
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Date Issued

2021-06-01

Publisher

Wiley

Published in
Natural Sciences
Volume

1

Issue

1

Article Number

e10010

Subjects

Condensed Matter Physics

•

Exciton Physics

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Many-Body Physics

•

Quasi-Particle Interactions

•

Semiconductors

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Time-Resolved Photoemission Spectroscopy

•

Ultrafast Dynamics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
DQML  
FunderGrant Number

Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada

Max Planck Society

H2020-EU.1.2.1

European Research Council (ERC) under the European Union

ERC-2015-CoG-682843

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Available on Infoscience
April 3, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/206991
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