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  4. Effects of simulated secondary organic aerosol water on PM 1 levels and composition over the US
 
research article

Effects of simulated secondary organic aerosol water on PM 1 levels and composition over the US

Kakavas, Stylianos
•
Pandis, Spyros N.
•
Nenes, Athanasios  
October 30, 2023
Atmospheric Chemistry And Physics

Water is a key component of atmospheric aerosol, affecting many aerosol processes including gas-to-particle partitioning of semi-volatile compounds. Water related to secondary organic aerosol (SOAW) is often neglected in atmospheric chemical transport models and is not considered in gas-to-particle partitioning calculations for inorganic species. We use a new inorganic aerosol thermodynamics model, ISORROPIA-lite, which considers the effects of SOAW, to perform chemical transport model simulations for 1 year over the continental United States to quantify its effects on aerosol mass concentration and composition. SOAW can increase average fine aerosol water levels by up to a factor of 2 when secondary organic aerosol (SOA) is a major PM (1) component. This is often the case in the south-eastern US, where SOA concentrations are higher. Although the annual average impact of this added water on total dry PM (1) concentrations due to increased partitioning of nitrate and ammonium is small (up to 0.1 mu g m (- 3) ), total dry PM (1) increases of up to 2 mu g m(- 3) (with nitrate levels increases of up to 200 %) can occur when RH levels and PM (1) concentrations are high.

  • Details
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Type
research article
DOI
10.5194/acp-23-13555-2023
Web of Science ID

WOS:001170527800001

Author(s)
Kakavas, Stylianos
Pandis, Spyros N.
Nenes, Athanasios  
Date Issued

2023-10-30

Publisher

Copernicus GmbH

Published in
Atmospheric Chemistry And Physics
Volume

23

Issue

21

Start page

13555

End page

13564

Subjects

Life Sciences & Biomedicine

•

Physical Sciences

•

Basis-Set Approach

•

Fine-Particle Ph

•

Particulate Matter

•

Megapoli Summer

•

Liquid

•

Winter

•

Size

•

Haze

•

Sensitivity

•

Emissions

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAPI  
FunderGrant Number

Horizon 2020

FORCeS

European Union

821205

Available on Infoscience
March 18, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/206542
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