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  4. Understanding and mitigating resistive losses in fired passivating contacts: role of the interfaces and optimization of the thermal budget
 
research article

Understanding and mitigating resistive losses in fired passivating contacts: role of the interfaces and optimization of the thermal budget

Libraro, Sofia  
•
Morisset, Audrey Marie Isabelle  
•
Hurni, Julien  
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October 11, 2023
Solar Energy Materials And Solar Cells

This work presents a study of p-type passivating contacts based on SiCx formed via a rapid thermal processing (RTP) step, using conditions compatible with the firing used to sinter screen-printed metallization pastes in industry. The contributions of the two interfaces (wafer/contact and contact/metal) to the contact resistivity are first decorrelated, identifying tunnelling at the wafer interface as the main contribution. We then investigate the influence of the active dopant concentration on the contact resistivity and the SiCx sheet resistance and propose strategies to reduce both resistances by increasing the thermal budget applied during RTP. Lastly, we discuss potentials and limitations of implementing the investigated stacks as rear side contacts of p-type devices with localized metallization. We demonstrate that increasing the thermal budget during RTP can effectively mitigate resistive losses and enhance contact performance and we show that an oxide layer that can withstand high thermal budgets is the key factor for obtaining simultaneously high passivation quality and good electrical properties. We investigate three different oxide types grown by HNO3 immersion, UV-O3 exposure and N2O plasma oxidation. The latter is demonstrated to be a promising candidate for an application in devices fabricated with high RTP thermal budget.

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Type
research article
DOI
10.1016/j.solmat.2023.112591
Web of Science ID

WOS:001159409300001

Author(s)
Libraro, Sofia  
•
Morisset, Audrey Marie Isabelle  
•
Hurni, Julien  
•
Genc, E.
•
Antognini, Luca  
•
Bannenberg, L. J.
•
Famprikis, T.
•
Ballif, C  
•
Hessler-Wyser, A  
•
Haug, F. -j.
Date Issued

2023-10-11

Publisher

Elsevier

Published in
Solar Energy Materials And Solar Cells
Volume

263

Article Number

112591

Subjects

Technology

•

Physical Sciences

•

Poly-Si

•

Rear Contacts

•

Resistance

•

Temperature

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
Available on Infoscience
March 18, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/206368
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