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research article

Control of Ge island coalescence for the formation of nanowires on silicon

Ramanandan, Santhanu Panikar  
•
Sapera, Joel Rene
•
Morelle, Alban
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February 12, 2024
Nanoscale Horizons

Germanium nanowires could be the building blocks of hole-spin qubit quantum computers. Selective area epitaxy enables the direct integration of Ge nanowires on a silicon chip while controlling the device design, density, and scalability. For this to become a reality, it is essential to understand and control the initial stages of the epitaxy process. In this work, we highlight the importance of surface treatment in the reactor prior to growth to achieve high crystal quality and connected Ge nanowire structures. In particular, we demonstrate that exposure to AsH3 during the high-temperature treatment enhances lateral growth of initial Ge islands and promotes faster formation of continuous Ge nanowires in trenches. The Kolmogorov-Johnson-Mehl-Avrami crystallization model supports our explanation of Ge coalescence. These results provide critical insight into the selective epitaxy of horizontal Ge nanowires on lattice-mismatched Si substrates, which can be translated to other material systems.|Schematics on the influence of Ge islands on the formation of continuous nanowires on silicon. In selective area epitaxy, islands with low density and low aspect ratio merge together to produce a continuous Ge nanowire on a silicon substrate.

  • Details
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Type
research article
DOI
10.1039/d3nh00573a
Web of Science ID

WOS:001161839400001

Author(s)
Ramanandan, Santhanu Panikar  
Sapera, Joel Rene
Morelle, Alban
Marti-Sanchez, Sara
Rudra, Alok  
Arbiol, Jordi
Dubrovskii, Vladimir G.
Fontcuberta I Morral, Anna  
Date Issued

2024-02-12

Published in
Nanoscale Horizons
Subjects

Physical Sciences

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Technology

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Quantum Dots

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Surface

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Growth

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Nucleation

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Kinetics

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Orientation

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Germanium

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Shape

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Gas

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Rds

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMSC  
FunderGrant Number

NCCR SPIN

National Centre of Competence (or Excellence) in Research - Swiss National Science Foundation

Swiss National Science Foundation

IZSEZ0-213059

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RelationURL/DOI

IsSupplementedBy

https://infoscience.epfl.ch/record/309619

IsSupplementedBy

10.5281/zenodo.10825476

IsSupplementedBy

https://doi.org/10.5281/zenodo.10825476
Available on Infoscience
February 23, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/205558
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