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  4. Persistence of Structural Distortion and Bulk Band Rashba Splitting in SnTe above Its Ferroelectric Critical Temperature
 
research article

Persistence of Structural Distortion and Bulk Band Rashba Splitting in SnTe above Its Ferroelectric Critical Temperature

Chassot, Frederic
•
Pulkkinen, Aki
•
Kremer, Geoffroy
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December 18, 2023
Nano Letters

The ferroelectric semiconductor alpha-SnTe has been regarded as a topological crystalline insulator, and the dispersion of its surface states has been intensively measured with angle-resolved photoemission spectroscopy (ARPES) over the past decade. However, much less attention has been given to the impact of the ferroelectric transition on its electronic structure, and in particular on its bulk states. Here, we investigate the low-energy electronic structure of alpha-SnTe with ARPES and follow the evolution of the bulk-state Rashba splitting as a function of temperature, across its ferroelectric critical temperature of about T-c approximate to 110 K. Unexpectedly, we observe a persistent band splitting up to room temperature, which is consistent with an order-disorder contribution of local dipoles to the phase transition that requires the presence of fluctuating dipoles above T-c. We conclude that no topological surface state can occur under these conditions at the (111) surface of SnTe, at odds with recent literature.

  • Details
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Type
research article
DOI
10.1021/acs.nanolett.3c03280
Web of Science ID

WOS:001140839400001

Author(s)
Chassot, Frederic
Pulkkinen, Aki
Kremer, Geoffroy
Zakusylo, Tetiana
Krizman, Gauthier
Hajlaoui, Mahdi
Dil, J. Hugo  
Krempasky, Juraj
Minar, Jan
Springholz, Gunther
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Date Issued

2023-12-18

Published in
Nano Letters
Volume

24

Issue

1

Start page

82

End page

88

Subjects

Physical Sciences

•

Technology

•

Arpes

•

Rashba Effect

•

Ferroelectric Transition

•

Snte

•

Electronic Structure

•

One-Step Calculations

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-SB-HD  
FunderGrant Number

, Austrian Science Fund

P30960-N27

Austrian Science Fund (FWF)

1/SOL/2021/2

Polish Ministry of Education and Science

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Available on Infoscience
February 21, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/205036
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