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  4. Rationalizing Performance Losses of Wide Bandgap Perovskite Solar Cells Evident in Data from the Perovskite Database
 
research article

Rationalizing Performance Losses of Wide Bandgap Perovskite Solar Cells Evident in Data from the Perovskite Database

Suchan, Klara
•
Jacobsson, T. Jesper
•
Rehermann, Carolin
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December 15, 2023
Advanced Energy Materials

Metal halide perovskites (MHPs) have become a widely studied class of semiconductors for various optoelectronic devices. The possibility to tune their bandgap (E-g) over a broad spectral range from 1.2 eV to 3 eV by compositional engineering makes them particularly attractive for light emitting devices and multi-junction solar cells. In this metadata study, data from Peer-reviewed publications available in the Perovskite Database () is used to evaluate the current state of E-g tuning in wideE(g) MHP semiconductors. Recent literature on wide E-g MHP semiconductors is examined and the data is extracted and uploaded onto the Perovskite Database. Beyond describing recent highlights and scientific breakthroughs, general trends are drawn from 45,000 individual experimental datasets of MHP solar cell devices. The historical evolution of MHP solar cells is recapitulated, and general conclusions are drawn about the current limits of device performance. Three dominant causes are identified and discussed for the degradation of performance relative to the Shockley-Queisser (SQ) model's theoretical limit for single-junction solar cells: 1) energetically mismatched selective transport materials for wide Eg MHPs, 2) lower optoelectronic quality of wide E-g MHP absorbers, and 3) dynamically evolving compositional heterogeneity due to light-induced phase segregation phenomena.

  • Details
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Type
research article
DOI
10.1002/aenm.202303420
Web of Science ID

WOS:001126548200001

Author(s)
Suchan, Klara
Jacobsson, T. Jesper
Rehermann, Carolin
Unger, Eva L.
Kirchartz, Thomas
Wolff, Christian Michael  
Date Issued

2023-12-15

Publisher

Wiley-V C H Verlag Gmbh

Published in
Advanced Energy Materials
Subjects

Physical Sciences

•

Technology

•

Database

•

Higher Bandgap

•

Metal Halide Perovskite

•

Open Circuit Voltage

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
FunderGrant Number

Helmholtz Association

2015-00163

Swedish Research Council

INCA 600398

Marie Sklodowska Curie Actions

HyPerFORME: 03XP0091

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Available on Infoscience
February 20, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204775
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