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  4. Nb, Ta and Hf-The tri-dopant tournament for the enhancement of TiO2 photochromism
 
research article

Nb, Ta and Hf-The tri-dopant tournament for the enhancement of TiO2 photochromism

Eglitis, Raivis
•
Kraukle, Annija
•
Kaambre, Tanel
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February 17, 2023
Journal Of Photochemistry And Photobiology A-Chemistry

TiO2 quantum dot (QD) size nanoparticle colloids have shown tremendous photochromic response. Here we show that the of the photochromic response of TiO2 QDs can be further enhanced by doping. Our synthesis approach allows to reach high nominal doping level by substituting up to 20 % of Ti in TiO2 without phase segregation simultaneously keeping particles in ultra-small. We compare the effect of different dopants (Nb5+, Hf4+ and Ta5+) on photochromic properties of TiO2 QDs. We show all dopants in study enhance the response kinetics and total transmittance change. From all three dopants, Nb5+ provides strongest response and fastest coloration while Hf4+ doped TiO2 QDs exhibit fastest recovery when the UV light is off. The presented insight in photochromic properties of doped TiO2 QDs will allow to develop photochromic devices and materials with better performance.

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Type
research article
DOI
10.1016/j.jphotochem.2023.114620
Web of Science ID

WOS:001010364000001

Author(s)
Eglitis, Raivis
Kraukle, Annija
Kaambre, Tanel
Smits, Krisjanis
Ignatans, Reinis  
Rubenis, Kristaps
Sutka, Andris
Date Issued

2023-02-17

Publisher

ELSEVIER SCIENCE SA

Published in
Journal Of Photochemistry And Photobiology A-Chemistry
Volume

439

Article Number

114620

Subjects

Chemistry, Physical

•

Chemistry

•

hf doped tio 2

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ta doped tio 2

•

nb doped tio 2

•

photochromism

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tio2 qds

•

anatase

•

size

•

nanoparticles

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nanocrystals

•

performance

•

strategies

•

particles

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titanium

•

oxides

•

zno

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
INE  
Available on Infoscience
July 3, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/198733
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