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  4. Fabrication of ZIF-8 membranes by direct assembly of nanosheets from bottom-up synthesis growth solution
 
research article

Fabrication of ZIF-8 membranes by direct assembly of nanosheets from bottom-up synthesis growth solution

Duan, Xueku
•
Kaya, Pinar
•
Chi, Heng-Yu  
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May 1, 2023
Journal Of Membrane Science Letters

Metal-organic frameworks (MOFs) host intrinsically porous structure and rich structural and chemical features. Several MOFs with pore aperture comparable to the size of gas molecules have attracted interest to form the selective layer of membranes. Synthesis of MOFs in nanosheet morphology is highly attractive for this because one can use highly-scalable filter coating to make MOF membranes. However, conventional nanosheet based processing route require several processing steps including centrifugation to prepare a coating dispersion. Herein, we report facile preparation of zeolitic imidazolate frameworks (ZIF) membranes by a straightforward assembly of nanosheets. ZIF-8 nanosheets were obtained by a direct bottom-up synthesis route where crystallization was optimized to obtain large, well-faceted 40-nm-thick nanosheets. Membranes, preferentially oriented along the c -out-of-plane direction, were fabricated by directly filtering the growth solution over a porous polymeric support without any further purification of nanosheets. This also ensures that only a small amount of precursor solution is used minimizing waste. The obtained membranes were compact and free of pinhole defects and yielded H2/C3H8 ideal selectivity over 3000 at 25 degrees C. We anticipate that this approach can be applied to several MOFs which can be synthesized in nanosheet morphology, advancing the scalability prospects of MOF membranes.

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Type
research article
DOI
10.1016/j.memlet.2023.100045
Web of Science ID

WOS:001011232500001

Author(s)
Duan, Xueku
Kaya, Pinar
Chi, Heng-Yu  
Topuz, Berna
Agrawal, Kumar Varoon  
Date Issued

2023-05-01

Publisher

ELSEVIER

Published in
Journal Of Membrane Science Letters
Volume

3

Issue

1

Article Number

100045

Subjects

zif-8 nanosheet

•

mof membranes

•

gas separation

•

polymeric support

•

scalable synthesis

•

metal-organic-framework

•

films

•

water

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAS  
Available on Infoscience
July 3, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/198674
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