Aqueous rechargeable zinc ion batteries (ZIBs) are regarded as a promising candidates for next-generation energy storage devices but strongly hindered by the limited utilization of the zinc metal anode (below 5%) due to the active water/anion corrosion. Herein, an ion selective and water-resistant cellulose nanofiber (CNF)/MXene composite membrane has been developed through molecular sieving to restrict active water and anions from the electrode/electrolyte interface through dehydration of zinc ions, avoiding the water/anion-induced corrosion/decomposition. In this way, the CNF/MXene@Zn anode exhibits significantly enhanced coulombic efficiency (99.5 % at 10 mA cm(-2)) and low voltage hysteresis. Moreover, coated with CNF/MXene composite membrane, zinc symmetric batteries can be operated at the extremely high current of 100 mA cm(-2) and ultra-high Zn utilization of 88.2% to achieve record-high cumulative plating capacity of 12 Ah cm(-2). Furthermore, the full vanadium dioxide (VO2) |CNF/MXene@Zn batteries exhibit a high capacity of 357 mAh g(-1) at 2 A g(-1) and retain 93.3% of the capacity after 500 cycles. Moreover, at negative/ positive capacity (N/P) ratio of 2.8, the CNF/MXene membrane coated zinc is able to stably cycle for 100 cycles, demonstrating the potential for high energy zinc battery. This designed CNF/MXene membrane enables ZIBs as viable energy storage devices for practical applications.