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research article

Swelling-Activated, Soft Mechanochemistry in Polymer Materials

Metze, Friederike Katharina  
•
Sant, Sabrina  
•
Meng, Zhao  
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February 27, 2023
Langmuir

Swelling in polymer materials is a ubiquitous phenomenon. At a molecular level, swelling is dictated by solvent-polymer interactions, and has been thoroughly studied both theoretically and experimentally. Favorable solvent-polymer interactions result in the solvation of polymer chains. For polymers in confined geometries, such as those that are tethered to surfaces, or for polymer networks, solvation can lead to swelling-induced tensions. These tensions act on polymer chains and can lead to stretching, bending, or deformation of the material both at the micro- and macroscopic scale. This Invited Feature Article sheds light on such swelling-induced mechanochemical phenomena in polymer materials across dimensions, and discusses approaches to visualize and characterize these effects.

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Type
research article
DOI
10.1021/acs.langmuir.2c02801
Web of Science ID

WOS:000939555500001

Author(s)
Metze, Friederike Katharina  
Sant, Sabrina  
Meng, Zhao  
Klok, Harm-Anton  
Kaur, Kuljeet  
Date Issued

2023-02-27

Publisher

AMER CHEMICAL SOC

Published in
Langmuir
Subjects

Chemistry, Multidisciplinary

•

Chemistry, Physical

•

Materials Science, Multidisciplinary

•

Chemistry

•

Materials Science

•

glycol) methacrylate) brushes

•

molecular brushes

•

surface patterns

•

tension

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mechanophore

•

forces

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mechanotransduction

•

instabilities

•

scission

•

probes

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LP  
Available on Infoscience
March 27, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/196416
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