Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Quantum-Mechanically Enhanced Water Flow in Subnanometer Carbon Nanotubes
 
research article

Quantum-Mechanically Enhanced Water Flow in Subnanometer Carbon Nanotubes

Ambrosetti, Alberto
•
Palermo, Giorgio  
•
Silvestrelli, Pier Luigi
December 1, 2022
Journal Of Physical Chemistry C

Water flow in carbon nanotubes (CNTs) starkly contradicts classical fluid mechanics, with permeabilities that can exceed no-slip Haagen-Poiseuille predictions by 2-5 orders of magnitude. Semiclassical molecular dynamics accounts for enhanced flow rates that are attributed to curvature-dependent lattice mismatch. However, the steeper permeability enhancement observed experimentally at about nanometer-size radii remains poorly understood, and suggests emergence of puzzling non-classical mechanisms. Here, we address water-CNT friction from a quantum mechanical perspective, in terms of water-energy loss upon phonon excitation. We find that combined weak water- phonon coupling and selection rules hinder water-CNT scattering, providing effective protection to water super flow, whereas comparison with a semiclassical theory evidences a friction increase that can exceed the quantum mechanical prediction by more than 2 orders of magnitude. Quasi-frictionless flow up to subnanometer CNTs opens new pathways toward minimally invasive trans-membrane cellular injections, single-water fluidics, and efficient water filtration.

  • Details
  • Metrics
Type
research article
DOI
10.1021/acs.jpcc.2c0717020174J
Web of Science ID

WOS:000892338900001

Author(s)
Ambrosetti, Alberto
Palermo, Giorgio  
Silvestrelli, Pier Luigi
Date Issued

2022-12-01

Published in
Journal Of Physical Chemistry C
Volume

126

Issue

47

Start page

20174

End page

20182

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

der-waals interactions

•

ab-initio

•

transport

•

van

•

fluctuations

•

friction

•

slippage

•

graphene

•

phonons

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
IPHYS  
Available on Infoscience
December 19, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/193315
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés