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research article

Decoding the Mechanisms of Phase Transitions from In Situ Microscopy Observations

Valleti, Sai Mani Prudhvi
•
Ignatans, Reinis  
•
Kalinin, Sergei, V
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September 5, 2022
Small

Analysis of the temperature- and stimulus-dependent imaging data toward elucidation of the physical transformations is an ubiquitous problem in multiple fields. Here, temperature-induced phase transition in BaTiO3 is explored using the machine learning analysis of domain morphologies visualized via variable-temperature scanning transmission electron microscopy (STEM) imaging data. This approach is based on the multivariate statistical analysis of the time or temperature dependence of the statistical descriptors of the system, derived in turn from the categorical classification of observed domain structures or projection on the continuous parameter space of the feature extraction-dimensionality reduction transform. The proposed workflow offers a powerful tool for the exploration of the dynamic data based on the statistics of image representation as a function of the external control variable to visualize the transformation pathways during phase transitions and chemical reactions. This can include the mesoscopic STEM data as demonstrated here, but also optical, chemical imaging, etc., data. It can further be extended to the higher dimensional spaces, for example, analysis of the combinatorial libraries of materials compositions.

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Type
research article
DOI
10.1002/smll.202104318
Web of Science ID

WOS:000849862000001

Author(s)
Valleti, Sai Mani Prudhvi
Ignatans, Reinis  
Kalinin, Sergei, V
Tileli, Vasiliki  
Date Issued

2022-09-05

Publisher

WILEY-V C H VERLAG GMBH

Published in
Small
Article Number

2104318

Subjects

Chemistry, Multidisciplinary

•

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Physics, Condensed Matter

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

ferroelectrics

•

in-situ heating

•

multivariate statistical analysis

•

phase transitions

•

scanning transmission electron microscopy

•

sliding window transform

•

dynamics

•

films

•

domains

•

challenges

•

glasses

•

growth

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
INE  
Available on Infoscience
September 12, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/190721
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