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  4. In Operando, Photovoltaic, and Microscopic Evaluation of Recombination Centers in Halide Perovskite-Based Solar Cells
 
research article

In Operando, Photovoltaic, and Microscopic Evaluation of Recombination Centers in Halide Perovskite-Based Solar Cells

Zohar, Arava
•
Kulbak, Michael
•
Turren-Cruz, Silver H.
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August 3, 2022
ACS Applied Materials & Interfaces

The origin of the low densities of electrically active defects in Pb halide perovskite (HaP), a crucial factor for their use in photovoltaics, light emission, and radiation detection, remains a matter of discussion, in part because of the difficulty in determining these densities. Here, we present a powerful approach to assess the defect densities, based on electric field mapping in working HaP-based solar cells. The minority carrier diffusion lengths were deduced from the electric field profile, measured by electron beam-induced current (EBIC). The EBIC method was used earlier to get the first direct evidence for the n-i-p junction structure, at the heart of efficient HaP-based PV cells, and later by us and others for further HaP studies. This manuscript includes EBIC results on illuminated cell cross sections (in operando) at several light intensities to compare optoelectronic characteristics of different cells made by different groups in several laboratories. We then apply a simple, effective single-level defect model that allows deriving the densities (N-r) of the defect acting as recombination center. We find N-r approximate to 1 x 10(13) cm(-3) for mixed A cation lead bromide-based HaP films and similar to 1 x 10(14) cm(-3) for MAPbBr(3)(Cl). As EBIC photocurrents are similar at the grain bulk and boundaries, we suggest that the defects are at the interfaces with selective contacts rather than in the HaP film. These results are relevant for photovoltaic devices as the EBIC responses distinguish clearly between high- and low-efficiency devices. The most efficient devices have n-i-p structures with a close-to-intrinsic HaP film, and the selective contacts then dictate the electric field strength throughout the HaP absorber.

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Type
research article
DOI
10.1021/acsami.1c08675
Web of Science ID

WOS:000835699700001

Author(s)
Zohar, Arava
Kulbak, Michael
Turren-Cruz, Silver H.
Nayak, Pabitra K.
Kama, Adi
Hagfeldt, Anders  
Snaith, Henry J.
Hodes, Gary
Cahen, David
Date Issued

2022-08-03

Publisher

AMER CHEMICAL SOC

Published in
ACS Applied Materials & Interfaces
Volume

14

Issue

30

Start page

34171

End page

34179

Subjects

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Science & Technology - Other Topics

•

Materials Science

•

defect states

•

diffusion length

•

p-i-n junction

•

br-based perovskite

•

ebic

•

ion migration

•

quantification

•

efficiency

•

diffusion

•

defects

•

voltage

•

light

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSPM  
Available on Infoscience
August 15, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/190094
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